Silicate-melt inclusions (MI) are small (~1-300 µm) blebs of silicate melt that are trapped within igneous phenocrysts (Fig. 1). They are glassy or crystalline, and are found within both extrusive and intrusive rocks. Because they can form at high pressures and are contained within relatively incompressible phenocryst hosts, they may retain high concentrations of volatile elements that normally escape from magmas during degassing. As such, analysis of these inclusions provides direct information on the volatile contents of magmatic systems.
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Figure 1. Transmitted-light photomicrographs of inclusions in quartz. (A) Silicate MI with negative crystal shape that reflects the bipyramidal habit of the host quartz. Note large (shrinkage?) bubble. From the Dolomite Mts. (Clochiatti 1975). (B) Multiple elongate silicate MI, most without bubbles, in quartz from Mont Dore (from Clocchiatti 1975). Field is 700 µm across. (C) Crystallized MI in quartz from Pantelleria (from Lowenstern & Mahood, 1991). Letter "q" shows quartz host, whereas "i" denotes inclusion. (D) The same MI after heating the host quartz for several hours at 850°C and atmospheric pressure. The inclusion is glassy and contains one very small bubble. (E) Three glassy, bubble-free MI of various sizes from Plinian fallout of the tuff of Pine Grove, Utah. (F) An empty inclusion (void) in quartz from the Plinian fallout of the tuff of Pine Grove. Such features are interpreted here to be leaked fluid inclusions that originally contained magmatic fluid/vapor, but no silicate melt (see section on Evidence for Trapped Fluids. |
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A number of recent papers have used silicate MI to understand magma degassing, to characterize the compositions of immiscible fluids separating from magmas, and to study petrogenetic processes such as magma mixing and crystal fractionation. Their use has allowed greater understanding of igneous geochemistry and magmatic processes (Table 1). This paper reviews the nature and characteristics of silicate MI, the tools and methods for their analysis, and some important findings of recent studies.
Several previous reviews have also addressed the general topic of MI and the interested reader is referred to these works. Clocchiatti (1975) reviewed optical and thermometric studies of MI in quartz and provides abundant observational and experimental data on the behavior of MI. Sobolev & Kostyuk (1975) synthesized the considerable volume of Russian literature on MI accumulated prior to 1975. Roedder (1979) gave a thorough discussion of silicate MI, their origins, and the methods of study and work to that date. Much of this information is repeated in his later, more general volume on fluid inclusions (Roedder 1984). Roedder (1992) summarized evidence for immiscible fluids in the magmatic environment. Johnson et al. (1994) discussed MI, and the information they provide about the pre-eruptive volatile contents of four magmatic systems; Kilauea, Mt. St. Helens, the Bishop tuff, and Mt. Pinatubo.
My review focuses on inclusions from andesitic to rhyolitic magmas and concentrates on those studies with information useful to economic geologists and hydrothermal geochemists who seek understanding of fluids emanating from igneous systems. The review consists of two parts; it begins with a primer on the characteristics of MI and methods by which they can be studied. The second half concentrates on recent studies and applications for petrologists and economic geologists.
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I. DATA OBTAINABLE FROM MI |
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1. Dissolved volatile concentrations in ore-forming and other magmas; H2O, CO2, Cl, S, F, B, Li and ore metals (See Table 2). |
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2. Minimum pressure of crystallization (e.g., Anderson et al. 1989). |
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3. Approximate temperature during crystallization (See Roedder 1984). |
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4. Evidence for exsolved fluids during crystallization of phenocrysts (e.g., Lowenstern 1994a). |
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5. Approximate (and partial) composition of coexisting exsolved fluids (e.g., Anderson et al. 1989; Wallace & Gerlach 1994; Lowenstern 1994b). |
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6. Evidence for magma mixing (e.g., Anderson 1976). |
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7. Composition of the melt phase in granites (Frezzotti 1992). |
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8. Time-scale of magmatism/volcanism (e.g., Bogaard & Schirink 1994). |
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II. DATA NOT OBTAINABLE FROM MI |
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1. The composition of the bulk magma (i.e., melt + phenocrysts + exsolved fluid). |
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2. Maximum pressure (depth) of entrapment. |
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3. Fate of fluids exsolved from the magma; mechanisms for fluid egress from magma. |
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4. Role of magma in formation of epithermal ore deposits (at least little direct information is available from silicate MI). |