Volcanic Gases and Their Effects
Magma contains dissolved gases that are released into the atmosphere during eruptions. Gases are also released from magma that either remains below ground (for example, as an intrusion) or is rising toward the surface. In such cases, gases may escape continuously into the atmosphere from the soil, volcanic vents, fumaroles, and hydrothermal systems.
At high pressures deep beneath the earth's surface, volcanic gases are dissolved in molten rock. But as magma rises toward the surface where the pressure is lower, gases held in the melt begin to form tiny bubbles. The increasing volume taken up by gas bubbles makes the magma less dense than the surrounding rock, which may allow the magma to continue its upward journey. Closer to the surface, the bubbles increase in number and size so that the gas volume may exceed the melt volume in the magma, creating a magma foam. The rapidly expanding gas bubbles of the foam can lead to explosive eruptions in which the melt is fragmented into pieces of volcanic rock, known as tephra. If the molten rock is not fragmented by explosive activity, a lava flow will be generated.
Together with the tephra and entrained air, volcanic gases can rise tens of kilometers into Earth's atmosphere during large explosive eruptions. Once airborne, the prevailing winds may blow the eruption cloud hundreds to thousands of kilometers from a volcano. The gases spread from an erupting vent primarily as acid aerosols (tiny acid droplets), compounds attached to tephra particles, and microscopic salt particles.
Volcanic gases undergo a tremendous increase in volume when magma rises to the Earth's surface and erupts. For example, consider what happens if one cubic meter of 900°C rhyolite magma containing five percent by weight of dissolved water were suddenly brought from depth to the surface. The one cubic meter of magma now would occupy a volume of 670 m3 as a mixture of water vapor and magma at atmospheric pressure (Sparks et. al., 1997)! The one meter cube at depth would increase to 8.75 m on each side at the surface. Such enormous expansion of volcanic gases, primarily water, is the main driving force of explosive eruptions.
The most abundant gas typically released into the atmosphere from volcanic systems is water vapor (H20), followed by carbon dioxide (C02) and sulfur dioxide (S02). Volcanoes also release smaller amounts of others gases, including hydrogen sulfide (H2S), hydrogen (H2), carbon monoxide (CO), hydrogen chloride (HCL), hydrogen fluoride (HF), and helium (He).
Examples of volcanic gas compositions, in volume percent concentrations
(from Symonds et. al., 1994)
Sulfur dioxide (SO2)
The effects of SO2 on people and the environment vary widely depending on (1) the amount of gas a volcano emits into the atmosphere; (2) whether the gas is injected into the troposphere or stratosphere; and (3) the regional or global wind and weather pattern that disperses the gas. Sulfur dioxide (SO2) is a colorless gas with a pungent odor that irritates skin and the tissues and mucous membranes of the eyes, nose, and throat. Sulfur dioxide chiefly affects upper respiratory tract and bronchi. The World Health Organization recommends a concentration of no greater than 0.5 ppm over 24 hours for maximum exposure. A concentration of 6-12 ppm can cause immediate irritation of the nose and throat; 20 ppm can cause eye irritation; 10,000 ppm will irritate moist skin within minutes.
Emission rates of SO2 from an active volcano range from <20 tonnes/day to >10 million tonnes/day according to the style of volcanic activity and type and volume of magma involved. For example, the large explosive eruption of Mount Pinatubo on 15 June 1991 expelled 3-5 km3 of dacite magma and injected about 17 million tonnes of SO2 into the stratosphere. The sulfur aerosols resulted in a 0.5-0.6°C cooling of the Earth's surface in the Northern Hemisphere. The sulfate aerosols also accelerated chemical reactions that, together with the increased stratospheric chlorine levels from human-made chlorofluorocarbon (CFC) pollution, destroyed ozone and led to some of the lowest ozone levels ever observed in the atmosphere.
At Kilauea Volcano, the recent effusive eruption of about 0.0005 km3/day (500,000 m3) of basalt magma releases about 2,000 tonnes of SO2 into the lower troposphere. Downwind from the vent, acid rain and air pollution is a persistent health problem when the volcano is erupting.
SO2 causes air pollution Volcanic smog
Eruptions of Kilauea Volcano release large quantities of sulfur dioxide gas into the atmosphere that can lead to volcanic air pollution on the Island of Hawai`i. Sulfur dioxide gas reacts chemically with sunlight, oxygen, dust particles, and water to form volcanic smog known as vog.
SO2 effects Earth's surface temperature Global cooling and ozone depletion
Measurements from recent eruptions such as Mount St. Helens, Washington (1980), El Chichon, Mexico (1982), and Mount Pinatubo, Philippines (1991), clearly show the importance of sulfur aerosols in modifying climate, warming the stratosphere, and cooling the troposphere. Research has also shown that the liquid drops of sulfuric acid promote the destruction of the Earth's ozone layer.
Hydrogen sulfide (H2S)
Hydrogen sulfide (H2S) is a colorless, flammable gas with a strong offensive odor. It is sometimes referred to as sewer gas. At low concentrations it can irritate the eyes and acts as a depressant; at high concentrations it can cause irritation of the upper respiratory tract and, during long exposure, pulmonary edema. A 30-minute exposure to 500 ppm results in headache, dizziness, excitement, staggering gait, and diarrhea, followed sometimes by bronchitis or bronchopneumonia.
Carbon dioxide (CO2)
Volcanoes release more than 130 million tonnes of CO2 into the atmosphere every year. This colorless, odorless gas usually does not pose a direct hazard to life because it typically becomes diluted to low concentrations very quickly whether it is released continuously from the ground or during episodic eruptions. But in certain circumstances, CO2 may become concentrated at levels lethal to people and animals. Carbon dioxide gas is heavier than air and the gas can flow into in low-lying areas; breathing air with more than 30% CO2 can quickly induce unconsciousness and cause death. In volcanic or other areas where CO2 emissions occur, it is important to avoid small depressions and low areas that might be CO2 traps. The boundary between air and lethal gas can be extremely sharp; even a single step upslope may be adequate to escape death.
CO2 trapped in depressions can be lethal to people and animals
When a burning piece of cloth is lowered into a hole that has a high concentration of CO2, the fire goes out. Such a condition can be lethal to people and animals.
Air with 5% CO2 causes perceptible increased respiration; 6-10% results in shortness of breath, headaches, dizziness, sweating, and general restlessness; 10-15% causes impaired coordination and abrupt muscle contractions; 20-30% causes loss of consciousness and convulsions; over 30% can cause death (Hathaway et. al., 1991).
Comparison of CO2 emissions from volcanoes vs.
Scientists have calculated that volcanoes emit between about 130-230 million tonnes (145-255 million tons) of CO2 into the atmosphere every year (Gerlach, 1999, 1991). This estimate includes both subaerial and submarine volcanoes, about in equal amounts. Emissions of CO2 by human activities, including fossil fuel burning, cement production, and gas flaring, amount to about 27 billion tonnes per year (30 billion tons) [ ( Marland, et al., 2006) - The reference gives the amount of released carbon (C), rather than CO2, through 2003.]. Human activities release more than 130 times the amount of CO2 emitted by volcanoes--the equivalent of more than 8,000 additional volcanoes like Kilauea (Kilauea emits about 3.3 million tonnes/year)! (Gerlach et. al., 2002)
Historical examples of the effects of carbon dioxide gas
- Mammoth Mountain in Long Valley Caldera, California kills trees near Mammoth Mountain, California
Hydrogen Chloride (HCl)
Chlorine gas is emitted from volcanoes in the form of hydrochloric acid (HCl). Exposure to the gas irritates mucous membranes of the eyes and respiratory tract. Concentrations over 35 ppm cause irritation of the throat after short exposure; >100 ppm results in pulmonary edema, and often laryngeal spasm. It also causes acid rain downwind from volcanoes because HCl is extremely soluble in condensing water droplets and it is a very "strong acid" (it dissociates extensively to give H+ ions in the droplets).
Hydrogen Fluoride (HF)
Fluorine is a pale yellow gas that attaches to fine ash particles, coats grass, and pollutes streams and lakes. Exposure to this powerful caustic irritant can cause conjunctivitis, skin irritation, bone degeneration and mottling of teeth. Excess fluorine results in a significant cause of death and injury in livestock during ash eruptions. Even in areas that receive just a millimeter of ash, poisoning can occur where the fluorine content of dried grass exceeds 250 ppm. Animals that eat grass coated with fluorine-tainted ash are poisoned. Small amounts of fluorine can be beneficial, but excess fluorine causes fluorisis, an affliction that eventually kills animals by destroying their bones. It also promotes acid rain effects downwind of volcanoes, like HCl.
Secondary Gas Emissions
Another type of gas release occurs when lava flows reach the ocean. Extreme heat from molten lava boils and vaporizes seawater, leading to a series of chemical reactions. The boiling and reactions produce a large white plume, locally known as lava haze or laze, containing a mixture of hydrochloric acid and concentrated seawater.
Laze plumes are very acidic
Extreme heat from lava entering the sea rapidly boils and vaporizes seawater, leading to a series of chemical reactions. The boiling and reactions produce a large white plume, locally known as lava haze or laze, which contains a mixture of hydrochloric acid (HCl) and concentrated seawater. This is a short-lived local phenomenon that only affects people or vegetation directly under the plume.
The hydrochloric acid (HCl) comes from the breakdown of seawater-derived chlorides during sudden boiling. Because the lava is largely degassed by the time it reaches the sea, any HCL coming from it is insignificant by comparison. Analyzed samples of the plume show that is is a brine with a salinity of about 2.3 times that of seawater and a pH of 1.5-2.0.
Key seawater chloride breakdown reactions that produce HCl gas
- MgCl2 (sea salt) + H2O
(steam) = MgO (periclase) + 2HCl (HCl gas)
- 2 NaCl (sea salt) + H2O
(steam) = Na2O (sodium oxide)
+ 2 HCL (HCl gas)
- CaCl2 (sea salt) + H2O (steam) = CaO (lime) + 2 HCL (HCl gas)
Avoid standing beneath a laze plume. Dense laze plumes, such as that shown here (Photograph by C.C. Heliker, February 10, 1994) contain as much as 10-15 parts per million of hydrochloric acid. These values drop off sharply as the plume moves away from the lava entry areas. During along-shore or on-shore winds, this plume produces acid rain that may fall on people and land along the coast. This rain (pH 1.5 to 2), often more acidic that lime juice or stomach acid, is very corrosive to the skin and clothing. Visitors to the lava entry areas should avoid standing directly in, under, or downwind of the laze plume.
Gerlach, T.M., 1999, Written communication.
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