Volcanic Sulfur Aerosols Affect Global Climate
and the Earth's Ozone Layer
Volcanic ash vs sulfur aerosols
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The primary role of volcanic sulfur aerosols in causing
short-term changes in the world's climate following some
eruptions, instead of volcanic ash, was hypothesized by
scientists in the early 1980's. They based their hypothesis
on the effects of several explosive eruptions in Indonesia
and the world's largest historical effusive eruption in Iceland.
Scientists studied three historical explosive eruptions
of different sizes in Indonesia--Tambora (1815), Krakatau
(1883), and Agung (1963). They noted that decreases in surface
temperatures after the eruptions were of similar magnitude
(0.18-1.3 °C). The amount of material injected into the
stratosphere, however, differed greatly. By comparing the estimated
amount of ash vs. sulfur injected into the stratosphere by each
eruption, it was suggested that the longer residence time of
sulfate aerosols, not the ash particles which fall out
within a few months of an eruption, was the paramount
controlling factor (Rampino and
Self, 1982).
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In contrast to these explosive eruptions, one of the most
severe volcano-related climate effects in historical times
was associated with a largely nonexplosive eruption that
produced very little ash--the 1783 eruption of Laki
crater-row in Iceland. The eruption lasted 8-9 months
and extruded about 12.3 km3 of basaltic lava over an
area of 565 km2. A bluish haze of sulfur aerosols
all over Iceland destroyed most summer crops in the country;
the crop failure led to the loss of 75% of all livestock and
the deaths of 24% of the population (H.
Sigurdsson, 1982). The bluish haze drifted east across
Europe during the 1783-1784 winter, which was unusually
severe.
Clearly, these examples suggested that the explosivity of
an eruption and the amount of ash injected into the stratosphere
are not the main factors in causing a change in Earth's
climate. Instead, scientists concluded that it must be
the amount of sulfur in the erupting magma.
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The eruption of El Chichon, Mexico, in 1982 conclusively
demonstrated this idea was correct. The explosive eruption
injected at least 8 Mt of sulfur aerosols into the atmosphere,
and it was followed by a measureable cooling of parts of the
Earth's surface and a warming of the upper atmosphere. A
similar-sized eruption at Mount St. Helens in 1980,
however, injected only about 1 Mt of sulfur aerosols into
the stratosphere. The eruption of Mount St. Helens injected much
less sulfur into the atmosphere--it did not result in a
noticeable cooling of the Earth's surface. The newly launched
TOMS satellite (in 1978) made it possible to measure these
differences in the eruption clouds. Such direct measurements
of the eruption clouds combined with surface temperatures
make it possible to study the corrleation between
volcanic sulfur aerosols (instead of ash) and temporary
changes in the world's climate after some volcanic eruptions.
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Volcanic interactions with the atmosphere

Figure modified by K.
McGee et. al., from R. Turco, in Volcanism and Climate Change,
1992
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The most significant impacts from large explosive eruptions
come from the conversion of sulfur dioxide
(SO2) to sulfuric acid
(H2SO4),
which condenses rapidly in the stratosphere to form fine sulfate
aerosols. The aerosols increase the reflection of radiation
from the Sun back into space and thus cool the Earth's lower
atmosphere or troposphere; however, they also absorb heat
radiated up from the Earth, thereby warming the stratosphere.
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Ozone depletion promoted by volcanic sulfur aerosols.
The sulfate aerosols also promote complex chemical reactions
on their surfaces that alter chlorine and nitrogen chemical
species in the stratosphere. This effect, together with
increased stratospheric chlorine levels from chlorofluorocarbon
(CFC) pollution, generates chlorine monoxide (ClO), which destroys
ozone (O3).
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USGS Global Change
Research Program
References
Sigurdsson, H., 1982, Volcanic pollution and climate--the
1783 Laki eruption: American Geophysical Union, EOS
Transactions, v. 10 August 1982, p. 601-602.
Rampino, M. R., and Self, S., 1982, Historic eruptions in
Tambora (1815), Krakatau (1883), and Agung (1963), their
stratospheric aerosols, and climatic impact: Quaternary
Research, v. 18, p. 127-143.
Self, S., Zhao, Jing-Xia, Holasek, R.E., Torres, R.C.,
and King, A.J., 1996, The
atmospheric impact of the 1991 Mount Pinatubo eruption,
in Newhall, C.G., Punongbayan, R.S. (eds.), 1996, Fire and
mud: Eruptions and lahars of Mt. Pinatubo, Philippines,
Philippine Institute of Volcanology and Seismology, Quezon
City and University of Washington Press, Seattle, 1126 p.
McGee, K.A., Doukas, M.P., Kessler, R. and Gerlach, T., 1997,
Impacts
of volcanic gases on climate, the environment, and people:
U.S. Geological Survey Open-File Report 97-262, 2 p.
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Last modification: 14 November 1999(SRB)